Thursday, March 26, 2020
Organic Chemistry - What Is Logarithmic Differentiation?
Organic Chemistry - What Is Logarithmic Differentiation?In organic chemistry, the symbol for logarithmic differentiation is the common logarithmic fractional scaling law, which means that to divide any expression by x, all exponents are multiplied by x. Logarithmic integral calculus (which is the core of all organic chemistry) uses a similar formula to compute all forms of polynomial integration.The author, Carl Zauner, has published the notation, in alphabetical order, as a textbook for the International Baccalaureate (IB) examination and also gives demonstrations for integration with the logarithmic differentiation formula. For example, here is the right-hand formula for the quadratic equation x3 - x2x - e - (3x2 - 2x) x - e.'To compute the logarithmic derivative, dividing by (3x2 - 2x) x - e, only need three values of x: x - e, x, and e'. Logarithmic differentiation is much more general than logarithmic integral calculus, because the quadratic equation above involves an expression that has both quadratic and exponential terms.Because of the logarithmic integral calculus, linear integration is far more convenient for quantitative analysis. It is, for example, the primary equation used in interpolation to get a more accurate coefficient in the equation for a triangulation.Let's sum up some of the other components of the logarithmic differentiation formula: x = a * exp(-x2), x2 = x - e, exp(-x2) = exp(-x2), e = x2 - x, and exp(-x) = x2. That is to say, we can write the logarithmic formula for a function by the combinations of the single symbols for x, e, and -x.As with the other properties of the logarithmic derivatives, logarithmic derivatives have very high precision. While no specific upper bound on the precision is known, logarithmic differentiation is so accurate that it will never lie even if a least-squares fit is used. In fact, when computing polynomial integrals, logarithmic differentiation is used in place of polynomial integration. In order to do int egration in the logarithmic system, we first multiply the integrand by the logarithmic integral.Synthetic organic chemistry textbooks use many symbols, but as the author admits, it is hard to keep track of all of them. In the example above, as we divide the quadratic function by the exponent of the derivative, we can multiply the logarithmic integral by the exponential term, leaving us with the appropriate polynomial coefficient to put in the quadratic. Thus, the square of the coefficient in the quadratic will give the factor of the integral, which is the natural logarithm. With these modifications, synthetic organic chemistry can be a lot easier!
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